题目：Interfacial engineering of Bi₁₂O₁₇Br₂/g-C₃N_4-x S-scheme junction boosting charge transfer for cooperative tetracycline decomposition and CO₂ reduction

作者：Haoyu Sun^a, Xuemei Jia^a,*, Jing Cao^a, Shifu Chen^a, Yong Chen^b, Haili Lin^a,b,*

单位：^aKey Laboratory of Green and Precise Synthetic and Applications, Ministry of Education; College of Chemistry and Materials Science, Key Laboratory of Clean Energy and Green Cycle, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China

^bKey Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences,Beijing, 100190, PR China

摘要：Although great progress has been made with respect to electron bridges, the electron mobility of the state-of-the-art electron bridges is far from satisfactory because of weak electrical conductivity. To overcome the above issue, cobalt phosphide (CoP), as a model electron bridge, was modified with superficial oxygen vacancies (OVs) and embedded into a defective bismuth oxychloride/carbon nitride (BiO_1-xCl/g-C₃N₄) Z-scheme heterojunction to obtain atomic-level insights into the effect of surface OVs on CoP electron bridges. Compared to BiO_1-xCl/g-C₃N₄ and bismuth oxychloride/cobalt phosphide/carbon nitride (BiOCl/CoP/g-C₃N₄) composites, the defective bismuth oxychloride/cobalt phosphide/carbon nitride (BiO_1-xCl/CoP/g-C₃N₄) heterojunction exhibited remarkable photocatalytic redox performance, indicating that the surface OVs-assisted CoP electron bridge effectively boosted electrical conductivity and yielded ultrafast electron transfer rates. The theoretical and experimental results demonstrate that the surface OVs play a critical role in improving the electrical conductivity of the CoP electron bridge, thereby accelerating electron mobility. This research provides insights into interfacial OVs-modified transition metal phosphide (TMP) electron bridges and their potential application in heterojunctions for energy crisis mitigation and environmental remediation.

影响因子：9.9

分区情况：一区

链接：https://doi.org/10.1016/j.jcis.2024.01.149